No. It's total carbs. The "of which sugars" part is basically useless; all carbs become sugars basically as soon as they enter your mouth (your saliva breaks down complex carbs into sugars long before they reach your stomach, especially if you chew).
And of course, since this isn't a stupid question but does suggest inexperience, if the nutrition table is "per 100g" or something like that, you need to work out how many MORE it will be for the total amount you're eating. i.e., if you're eating 200g of the food, then you double whatever it says for 100g.