The Libre can take 24-48 hrs to settle down so you could find the readings improve as yet. However, all meters, ie blood glucose meters, test strips etc will often give a different reading, even if from the same blood sample. There are many factors causing slight differences.
The Glucometers and the Libre have a % range of tolerance to be acceptable. Sorry, I can't quote you the figures but you can find this info out on Google etc, or even in the forum here, but you may have to read back a bit.
Many people attach the new sensor 24 hours before the current one expires and then activates the new sensor once the old one has finished.
If you are still concerned re the accuracy of the sensor, give Abbott a call and they will explain the tolerance %. Most people seem to find the sensor to be pretty accurate, although not necessarily the same as your meter. Because the finger-prick is a test on the blood, the Libre is sampling interstitial fluid, so there is a basic difference in the test itself. Also, being interstitial fluid, it will take a bit longer to reflect the blood glucose level. The extremes, ie higher figures and the lower figures may show more discrepancy too. If the blood glucose level is changing very quickly, ie raising or lowering quickly, again the Libre sensor won't pick up the changing levels of glucose as quickly as the blood test and therefore will likely show a larger discrepancy. Body hydration also plays a huge part in the accuracy of the readings so may I suggest you make sure to be drinking lots of water to keep well hydrated.
Give the sensor a bit longer and then see how it goes. It could be that your glucometer reads a bit high or low took, of course