I've used both.
I started with the Libre and loved it. Really quite accurate, once you got your head around the delay in the reading. Easy to install, test as often as you like, readings stored for overnight & trend information. Two weeks life for the sensor made it just about affordable, given the benefits. I had to stop using it as I developed an allergy to either the adhesive or the filament, meaning that sensors kept coming off and leaving a horrible mess underneath. Whilst, Abbotts were very good at replacing, the itchyness and sores left made it impossible to continue.
Currently, I'm using the G5, made possible by not having to buy the receiver and the special offer available to new users. Firstly, installing is a bit different to the Libre, but is just a painless. If you've used Libre putting the sensor in is no harder. You just need to follow the steps on the installation video. Once installed with the transmitter installed, I found no problem pairing the phone & transmitter. There's a 2 hour warm up, followed by a call for two blood sugar readings for calibration. I've found, with the first sensor, that the first week was very accurate, rate of change and alarm settings worked a treat.
At the end of the first week, I restarted the sensor, in common with many others. This hasn't been as successful as others have found, with the sensor being poor at rate of change and often a couple of units out (bearing in mind the time differences between blood and interstitial fluid). The sensor is still giving readings at the moment so I'll keep going with it until it shows the signs that it's done for. I will persevere with the other 3 sensors, though, and make a decision after that. Financially for me, this will only work out if I can make the sensors last 2 weeks at a time. Occasional use id also ruled out by the transmitter's 3 month life. There has also been no irritation or feeling that the sensor is going to come loose.
Sorry if this is a bit long winded, hope it helps.