My guess would be because there is no calibration facility for the Libre system.
Basically with the Dexcom setup, you calibrate once or twice per day from a finger prick test so the system can adjust itself to suit the individual from the reference BGL value inputted to the receiver.
The Libre has no way to calibrate itself so it's a "one size fits all" system. It has an algorithm to convert interstitial fluid data into a BG reading in either mmol/L or mg/dL. I'd imagine that this algorithm would struggle with accuracy when attached to the body of a small child vs that of a fully grown adult. In other words the algorithm has been constructed in such a way to suit the vast majority of people.
How much of the above is true I don't know as it's only my guess. I can't imagine it'll be long until sensors for small children become available.
I'm sure someone clever will come along and give the definite reason for this. Until then you'll have to tolerate my guesswork
Grant