It's fairly normal to have differing results in the first 24-48 hrs - that's why some people apply a sensor and leave it un-activated for that time, I believe this period is caused by the healing process around the filament.
If you want to change to using the Libre as a blood tester then do so, saves carry around 2 devices - bear in mind all 3 will potentially have differing results anyway*. You'd need to request the Freestyle Optium testing strips.
*All Blood Glucose testing devices should be within ~15% of the actual BG (the Libre should also but as it doesn't measure BG it can have a time lag which for tries it to account for, but can also under and over estimate when actual BG is not near normal range or during rapid BG fluctuations.