Yes, DAFNE will start you out on 1 unit per 10g of carb. But DAFNE is very much about a basal/bolus regime (ie background insulin is involved too) and you say you're not using background insulin yet? - so I'm not sure if it will work for you.
DAFNE also will counsel you to check bg before meals, ie not to worry aboaut the 2-hours-after-eating bg. So this may not suit you, if you feel ill when you get post-meal spikes.
The DAFNE blood sugar targets are as follows:
before breakfast: 5.5 - 7.5
before other meals: 4.5-7.5
before bed: 6.5-8.0
They also say, as a rough guide, that 1 unit of quick acting can lower your bg by 2-3 mmols, and 10g of carbohydrate can raise it by 2-3 mmols. I would add though that this is just a starting point; you need to work out what actually happens in your body. We are all different.
Although they start you off on 1:10g, I know of people who have had to go down to 0.5:10g, and also people who may need to be on as much as 3:10g, especially in the morning. So it's a very individual thing. Write out your blood sugars and compare them with the DAFNE targets, and see if you can see a pattern. Don't change your ratio immediately you have a high bg, keep things as constant as possible and watch it for a couple of days before adjusting the ratio. And if you can, try to avoid chasing those post-meal bg spikes, at least until you have your overall ratios right. Getting the meal time bgs in target is kind of the first step. Worry about the rest later.
There you go - DAFNE in a nutshell - let us know if it helps at all!