Total carbohydrate values include the weight of all sugars, sugar alcohols, fiber and any other carbohydrate-based ingredient like maltodextrins. When this is high, treat with caution.
The sugars amount includes sugars that are present naturally in the food such as lactose in milk and fructose in fruit, sucrose in fruits and vegetables, as well as sugars added to the food during processing, such as sugar / sucrose, corn syrup, honey, high fructose corn syrup, fruit juice concentrates and dextrose. When this is high, avoid it.
Not all carbs are turned into glucose, just about all beta carbs are indigestable and some alpha carbs in the oligosaccharide group are only partially digestible, so they won't make much of a difference to your BG levels.
Not all sugars will get turned into glucose either. Lactose in milk is digestible by most people in northern europe but it is quite different in southern europe. Even in the UK, 15% can't digest it. If you look at some of artifical sugars, you will see that they have very high contents, eg Truvia is 99% but, it has no calories, because you do not digest any of it.
However, food labelling cannot give a breakdown of the different types of carbohydrates; monosaccharides, disaccharides, oligosacchardies and polysaccharides and a list of the various alpha and beta carbohydrate types, because most people don't know what they are. What we see, carbs, sugars and fibre is only a very rough guide.
Having a little bit and testing to see what effect it had is the best guide because, all humans are different. Even non diabetics say 'I avoid that food, it doesn't agree with me'. Diabetics are just a bit more finicky with what they can or cannot eat,