This is NOT the time to calibrate.
Given the known limitations of CGMs, the time to calibrate is when your BG is stable (not rising or falling), when there are no external events (recent food, bolus insulin still active, exercise, stress, etc) which could change the stability and when your BG is between about 5 and 10.
Calibrating, for example, when the CGM when it is reporting a compression low will cause all future readings to be too high.
I always check my BG with a finger prick before going to bed, at least 4 hours after my last meal and last bolus and exercise. If my BG is "in range", I will calibrate my sensor. This allows me to make minor adjustments every evening and gives me confidence through the night.